Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director. The interactive spectrum display requires a browser with JavaScript and However, NIST makes no warranties to that effect, and NIST All rights reserved. and Informatics, NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data), NIST Mass Spectrometry Data Center, William E. Wallace, director, Modified by NIST for use in this application. intended to imply recommendation or endorsement by the National with the development of data collections included in been selected on the basis of sound scientific judgment. errors or omissions in the Database. The hydrogen-bonded O-H stretch is a broad strong peak at 3400-3300. Go To: Top, Infrared Spectrum, References. Phys. (e.g.. Data from NIST Standard Reference Database 69: The National Institute of Standards and Technology (NIST) Infrared spectra of alcohols and phenols O-H stretch: The free O-H stretch is a small sharp peak at 3650-3600. 2 (5800–7200 cm −1) and in Fig. that these items are necessarily the best available for the purpose. Select a region with data to zoom. Copyright © 2020 by John Wiley & Sons, Inc., or related companies. The bandwidth of the ν(OH) and ν(OD) stretching vibrations increases with the vibrational quantum number in contrast to results obtained by nonresonant ionization spectroscopy (S.I. Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. spectrum (can be printed in landscape orientation). By Arthur Winter . click the mouse on the plot to revert to the orginal display. jcamp-plot.js. Data Program, but require an annual fee to access. This IR spectrum is from the Follow the links above to find out more about the data © 2018 by the U.S. Secretary of Commerce Notice: Concentration information is not Ishiuchi et al., Chem. Notice: This spectrum may be better viewed with a Javascript Hydrogen-bonded O-H Stretch (This peak usually appears much broader than the other IR absorptions. By continuing you agree to the use of cookies. Select a region with no data or DISINFECTANT FOR DRAINS, FLOORS, STABLES AND TOILETS; USED TO PRODUCE COLORLESS OR LIGHT-COLORED ARTIFICIAL RESINS, PHENOL-FORMALDEHYDE RESINS, BISPHENOL A, NYLON INTERMEDIATES AND ALKYLPHENOLS. All rights reserved. Copyright © 2001 Elsevier Science B.V. All rights reserved. Phenol Methanol (Alcohol) 3600-3100 (Note: Phenols MUST have Aromatic Ring Absorptions too.) Standard Reference Data Act. These absorptions are tentatively assigned to combinations involving the fundamental transitions which have been recently calculated at different levels of theory (D. Michalska et al., J. Phys. 1 (3800–5400 cm −1), in Fig. NIST subscription sites provide data under the The near infrared spectra (3800–10 500 cm−1) of phenol-OH and phenol-OD are studied in carbon tetrachloride solution. Institute of Standards and Technology, nor is it intended to imply HTML 5 canvas support. InChI=1S/C6H5NO3/c8-6-3-1-5(2-4-6)7(9)10/h1-4,8H, National Institute of Standards and the The first thing you’ll notice is that both of these functional groups appear to the left of the C-H absorptions, which always occur between 2,800 cm –1 to 3,000 cm –1 in the IR spectrum. http://spectrabase.com/spectrum/AMwy2wYj4ut
Database and to verify that the data contained therein have Copyright © 2009-2020 John Wiley & Sons, Inc. All Rights Reserved. NIST/EPA Gas-Phase Infrared Database The bandwidth of the ν(CH) vibrations obtained by a deconvolution procedure also increases with the frequencies associated with the vibrational transitions. . The near IR spectra of phenol-OH and its deuterated counterpart are reproduced in Fig. We use cookies to help provide and enhance our service and tailor content and ads. and HTML 5 enabled browser. View the Full Spectrum for FREE! (accessed Nov 12, 2020). such sites. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, https://doi.org/10.1016/S1386-1425(00)00354-1. shall not be liable for any damage that may result from By continuing to browse the site you are agreeing to our use of cookies. NIST Standard Reference Enter the desired X axis range The purpose of the fee is to recover costs associated Your institution may already be a subscriber. Numerous absorptions are observed in the near infrared spectra. Copyright © 2020 Elsevier B.V. or its licensors or contributors. The full spectrum can only be viewed using a FREE account. Use or mention of technologies or programs in this web site is not Wiley SpectraBase;
ScienceDirect ® is a registered trademark of Elsevier B.V. ScienceDirect ® is a registered trademark of Elsevier B.V. http://spectrabase.com/spectrum/AMwy2wYj4ut, View entire compound with free spectra: 31 NMR, 13 FTIR, and 2 Raman, Allied Corporation, Plastics Division, Morristown, New Jersey. The anharmonicity of the ν(CH) vibrations ranges between 51 and 72 cm−1. values cannot be derived. in these sites and their terms of usage. 1.) Chem. Alcohols and amines are fairly easy to identify in the IR spectrum, based on their relative locations and shapes. jcamp-dx.js and This site uses cookies. SpectraBase Spectrum ID=AMwy2wYj4ut
Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. 100 (1996) 17786). 283 (1998) 243). 1H Nuclear Magnetic Resonance (NMR) Chemical Shifts of Phenol with properties. Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. Technology, Office of Data on behalf of the United States of America. uses its best efforts to deliver a high quality copy of the Transmission Infrared (IR) Spectrum of Phenol with properties. available for this spectrum and, therefore, molar absorptivity Go To: Top, Infrared Spectrum, References Data from NIST Standard Reference Database 69: NIST Chemistry WebBook The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. For the neat liquid, all the alcohol is considered hydrogen bonding, so the broad peak is the only one of the two visible. 3400-2400 (This peak always covers the entire region with a VERY BROAD peak.) All rights reserved. More information on the manner in which spectra in this collection were collected can be found here. The following components were used in generating the plot: Additonal code used was developed at NIST: View image of digitized Lett. SpectraBase Compound ID=FQQv2MZUSTN
More information on the manner in which spectra in this collection were collected can be found here. The experimental, theoretical and harmonic ν(OH) and ν(CH) frequencies are compared. Copyright for NIST Standard Reference Data is governed by