View desktop site, Lab Report, Modified Date: REDUCTION OF VANILLIN: Preparation of Vanillyl alcohol PARTI Name: + 12 MUID: Chemical Equation: (show all structures, not empirical formulas; +3 pts.) The actual melting point was 115°C, which was approximately 25 degrees higher than the experimental values. Borohydride as the reducing agent in order to determine the percentage yield, melting point and Experiment 6: Reduction of Vanillin Report Worksheet 5. O. NaBH, H,0 2 HCLHO lil 1. LAB GROUP THURS; 1000-1300HRS DATE 05/03/ EXPERIMENT NO. 334. 3. ... report of results. Privacy vanillin, 1, and sodium borohydride, and the product, vanillyl alcohol, 2. Although many different On each spectrum, draw the structure of the compound, and identify any signals that you can. Note that there will be … Procedure In a 50-mL beaker, dissolve vanillin (8.0 mmol, 1.0 g) in 1 M aqueous NaOlå (7 mL). 110 2. © 2003-2020 Chegg Inc. All rights reserved. You can get your Spectroscopy: Attach the following spectra to this report. CHEM12B – Section 202 Spring 2019 Maria Bedolla 10/22/2019 Reduction of an Aldehyde (Vanillin II) Lab Report I: Introduction The purpose of this experiment was to reduce the carbonyl group of vanillin, 4-hydroxy-3-methoxybenzaldehyde, to vanillyl alcohol, and compare the IR spectra of vanillin and vanillyl alcohol. After the time period, the flask was cooled in an ice-water bath and 3 M HCl was added dropwise with swirling. The crystals were allowed to air dry for several minutes while suction continued to eliminate excess water. According to Senior and Swailes (2010, p. 6) "the forces that operate. In this experiment, p-vanillin will be treated with a reducing agent to produce vanillyl alcohol. & Mass Of Flask And Vanillin: NA 8 3. a.k.a. 2467 g| Melting Point Range of Vanillyl Alcohol| 75-90°C| Percent Yield| 63. Mass of synthesized Vanillyl alcohol: 7. HILO NaBHHO 2 HCLHO ☺ an 1. Two insect species, the African sugar-cane borer moth3 and the Leaffooted pine seed bug,4 utilize vanillyl alcohol in its Reduction of Vanillin to Vanillyl Alcohol . PhDessay is an educational resource where over 1,000,000 free essays are collected. Reduction of Vanillin to Vanillyl Alcohol . This lab report recaps the procedure and results of the lab. Don’t miss a chance to chat with experts. Do the same for vanillin (spectra available on Blackboard). Mass of vanillin: 4. Expt 3: Reduction of Vanillin with Sodium Borohydride to form Vanillyl Alcohol INTRODUCTION One of the most commonly used methods for preparing 1º and 2º alcohols is the reduction of aldehydes [equation (1)] or ketones [equation (2)]. Academia.edu is a platform for academics to share research papers. 5 mL of 1 M NaOH solution in a 25 mL Erlenmeyer flask. Privacy vanillyl alcohol m.p. Retrieved from https://phdessay.com/borohydride-reduction/. The mechanism of the lab involved reduction. MW Of Vanillin: Mol: MW Of Vanillyl Alcohol: 5. Melting point (experimental): 9. 110-117C Vanillyl alcohol, which is made by the reduction of vanillin, shows promise as a renewable starting material for the synthesis of biologically active molecules and flavoring ingredients. Other chemical processes included in the lab were recrystallization, melting point, and extraction. LAIN 2. Mass Of 125 Ml. 9%. HCl then reacted with the negative oxygen on vanillin, and the oxygen then became protonated, which made another alcohol on the benzene ring. H. 10. https://phdessay.com/borohydride-reduction/, “Let me hear it from the beginning,” said Inspector Dulles. Book Report Camp Rock: Stage Fright By: N. B. Since Bob is thinking of. The solution was gently cooled and the side of the flask was gently scratched with a glass rod to induce recrystallization. % 8. HCLHO مر 1. The melting point range obtained for vanillyl alcohol was between 75-90°C. Procedure In a 50-mL beaker, dissolve vanillin (8.0 mmol, 1.0 g) in 1 M aqueous NaOlå (7 mL). Reference of literature mp: (+1 pt.) IR: Include IR spectra for both of vanillin and vanillyl alcohol (both posted on Blackboard). HCI, HO INOBHG,H,O 2. Mass Of Vanillin: 4. ... report of results. H. 10. HCl OH HO H 3CO Vanillin, 1 Vanillyl alcohol, 2 4 (3) Either LiAlH4 and NaBH4 could be used for this reduction, but sodium borohydride is the reagent of choice … John Heger CMY 211 Lab Section 13 11-30-2011 Borohydride Reduction of Vanillin to Vanillyl Alcohol Introduction: The purpose of this lab was to reduce vanillin to vanillyl alcohol. The round bottomed flask is then clamped above the magnetic stirrer. Mass of 125 ml. custom paper from our expert writers, Borohydride Reduction. The chemical process studied in this lab was reduction, the process of reducing the number of bonds to oxygen and increasing the number of bonds to hydrogen. g/mol (+2 pts.) The aim of the experiment is to carry out a reduction of vanillin to vanillyl alcohol using Sodium. Remember. Terms Erlenmeyer Flask: NA 2. The solution was allowed to stand undisturbed for 30 minutes at room temperature. 3. Conclusion: Vanillin was reduced to vanillyl alcohol which obtained a melting point of 75-90°C. 1. Responsible for the flavour and aroma of vanilla Perfume: Coconut, cream, milk, balsam “ H ”: Nucleophile or Base? This is just a sample. MW of vanillin: mol: MW of vanillyl alcohol: 5. The dried crystals were weighed and a melting point was obtained. 'H NMR: In a single Delta file, superimpose the 'H NMR spectra of vanillin (available on Blackboard) and vanillyl alcohol. 2.47 8 6. Experiment 6: Reduction of Vanillin Report Worksheet 5. Terms Mass Of Vanillin: 4. HCI HO. Experiment 6: Reduction Of Vanillin Report Worksheet 5. LAIH 2. Mass Of Flask And Vanillin: NA 8 3. Vanillyl alcohol, the product formed by the reduction of vanillin, is a promising renewable starting material for the synthesis of biologically active molecules and flavoring ingredients. Although many different Responsible for the flavour and aroma of vanilla Perfume: Coconut, cream, milk, balsam “ H ”: Nucleophile or Base? It is the main component of both natural and artificially produced vanilla extracts 1.Vanillin can be reduced through sodium borohydride (NaBH 4 ), as well as lithium aluminumhydride (LiAlH 4 ), to produce vanillyl alcohol—a molecule that is widely used in the flavoring ofdifferent foods. Don't use plagiarized sources. Erlenmeyer Flask: NA 2. Percent yield ((()) x 100 (+ 2 pts.) HICIO Nabi. 99 % yield| Discussion: The purpose of this lab was to reduce vanillin to vanillyl alcohol. Results: Table 1: Experimental Data Table Initial Mass of Vanillin| 0. HCIO 1. 'H NMR: In a single Delta file, superimpose the 'H NMR spectra of vanillin (available on Blackboard) and vanillyl alcohol. Answer all questions in the Hands-on MIS project. Results: 1. Special Hazards NaBH4 is flammable and corrosive. LIAIRE 2. H O HO H 3CO 1. Assign the signals to the best of your ability. It was added in three to four portions over a period of 3 minutes. Melting point (literature value): NA 110 - 117 "C "C 10. Vanillin ... MW 37.83 Vanillyl Alcohol MW 154.06 C. 8. Question: Lab Report, Modified Date: REDUCTION OF VANILLIN: Preparation Of Vanillyl Alcohol PARTI Name: + 12 MUID: Chemical Equation: (show All Structures, Not Empirical Formulas; +3 Pts.) © 2003-2020 Chegg Inc. All rights reserved. 6. Calculate the millimoles in 0.13 g of NaBH4 and the theoretical yield of vanillyl alcohol. The mechanism involved the reduction of vanillin to vanillyl alcohol, which increased the number of bonds to hydrogen and decreased the number of bonds to oxygen by the reduction of a carbonyl. Results: 1. The crude product was suction filtered using a Buchner or Hirsch funnel and was washed with three small portions of cold water. John Heger CMY 211 Lab Section 13 11-30-2011 Borohydride Reduction of Vanillin to Vanillyl Alcohol Introduction: The purpose of this lab was to reduce vanillin to vanillyl alcohol. The typical C O stretch of an aldehyde is 1720-1750 cm', whereas that for vanillin is near 1660 cm!. vanillin, 1, and sodium borohydride, and the product, vanillyl alcohol, 2. NaBH 4, NaOH 2. Spectroscopy: Attach the following spectra to this report. Preparation of vaniliyi alcohol + 38 PRACTICE PROBLEMS: PART 2 Predict the Product: Predict the major organic product(s) for the following reactions. Sodium borohydride was used to reduce the aldehyde on the vanillin molecule, which left the oxygen with a negative charge.