Van Stipdonk, J. Oomens, N. Polfer, D. T. Moore, W. A. de Jong, M. E. McIlwain. Gas-phase infrared spectra of cationized nitrogen-substituted polycyclic aromatic hydrocarbons. downloaded The gas-phase complexes M+(acet)2, where M is Fe, Co, or Ni and acet is acetophenone, were studied spectroscopically by infrared multiple-photon dissociation (IRMPD) supported by density functional (DFT) computations. Fe+ complexes appeared largely O-bound, but with clear evidence for some R-binding. Groenewold, A.D. Appelhans, M.E. [13] In humans, acetophenone is metabolized to benzoic acid, carbonic acid, and acetone. Binding sites, rotational conformers, and electronic states of Sc–C[sub 6]H[sub 5]X (X=F, CH[sub 3], OH, and CN) probed by pulsed-field-ionization electron spectroscopy. The exceptionally large extent of R binding for Co+ highlights the special affinity of this metal ion for aromatic ring ligands. Commercially significant resins are produced from treatment of acetophenone with formaldehyde and a base. by Eric Martz from the original by Motyka, Lahti and Lancashire. For Ni+, O binding was found to predominate (similar to the previously studied Cr+ case), with less than ∼10% of R-bound ligands in the population. Robert These substances are components of coatings and inks. Infrared multiple photon dissociation spectroscopy of ions in Penning traps. The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Do coinage metal anions interact with substituted benzene derivatives?. Spectroscopy Data Tables 1 Z:\files\classes\spectroscopy\typical spectra charts.DOC Infrared Tables (short summary of common absorption frequencies) The values given in the tables that follow are typical values. IR spectroscopic characterization of intermediates in a gas-phase ionic reaction: The decarbonylation of Co+(acetophenone). Robert C. Dunbar, Jeffrey D. Steill, and Jos Oomens . Michael J. van Stipdonk, Partha Basu, Sara A. Dille, John K. Gibson, Giel Berden, and Jos Oomens . Encapsulation of Metal Cations by the PhePhe Ligand: A Cation−π Ion Cage. IR-Spectroscopic Characterization of Acetophenone Complexes with Fe, Department of Chemistry, Case Western Reserve University, Cleveland, Ohio 44106, and FOM Institute for Plasma Physics “Rijnhuizen”, Edisonbaan 14, 3439MN Nieuwegein, The Netherlands. Cation−π Interactions in Protonated Phenylalkylamines. Binding of Divalent Metal Ions with Deprotonated Peptides: Do Gas-Phase Anions Parallel the Condensed Phase?. Production. Your Mendeley pairing has expired. Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. Specific bands may fall over a range of wavenumbers, cm-1. , Ag The FELIX free electron laser was used to give tunable radiation from ∼500 to 2200 cm-1. Optical Chemical Sensor and Electronic Nose Based on Porphyrin and Phthalocyanine. Structures, energetics, and dynamics of gas phase ions studied by FTICR and HPMS. the Altmetric Attention Score and how the score is calculated. To whom correspondence should be addressed. Barbara Chiavarino, Maria Elisa Crestoni, Markus Schütz, Aude Bouchet, Susanna Piccirillo, Vincent Steinmetz, Otto Dopfer, and Simonetta Fornarini . Please explain. π,,,,,,,,, The typical dosage was 0.12 to 0.3 milliliters. 2+ You’ve supercharged your research process with ACS and Mendeley! for local installation for non-profit academic use only. –Cs Acetophenone is the organic compound with the formula C 6 H 5 C(O)CH 3 (also represented by the pseudoelement symbols PhAc or BzMe).